Addition: CH Activation in S-Alkenyl Sulfoximines: An Endo 1,5-Hydrogen Migration
نویسندگان
چکیده
منابع مشابه
Alkene 1,2‐Difunctionalization by Radical Alkenyl Migration
Transition-metal-free radical α-perfluoroalkylation with the accompanying vicinal β-alkenylation of unactivated alkenes is presented. These radical cascades proceed by means of 1,4- or 1,5-alkenyl migration by electron catalysis on readily accessed allylic alcohols. The reactions comprise a regioselective perfluoroalkyl radical addition with subsequent alkenyl migration and concomitant deproton...
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2012
ISSN: 1433-7851
DOI: 10.1002/anie.201206823